Solid solutions of perovskite in the LaO1.5–BaO–ScO1.5–ZrO2 system at 1600 °C

A partial pseudoternary phase diagram of the LaO1.5–BaO–ScO1.5 system was established at 1600 °C. According to the phase diagram, the solubility of barium into the cubic perovskite phase (LaScO3) at 1600 °C is 0.24 in a mole fraction of barium oxide (XBaO) on the composition line where the mole fraction of scandium oxide is 0.50. Another cubic perovskite phase (BaZrO3) in the BaO–ZrO2–ScO1.5 system is also known. We investigated the phase relationships between the two cubic perovskites in the pseudoquaternary phase diagram of the LaO1.5–BaO–ScO1.5–ZrO2 system. As a result, we found the existence of a wide solid solution region between the cubic perovskites at 1600 °C. The region was determined by X-ray diffraction (XRD) analysis and energy dispersive X-ray (EDX) microanalysis of samples with various compositions, and established the partial pseudoquaternary phase diagram.

Graphical abstractThe phase boundary of solid solution between lanthanum scandate and barium zirconate at 1600 °C was clarified by establishing a partial pseudoquaternary phase diagram of the LaO1.5–BaO–ScO1.5–ZrO2 system at 1600 °C.Figure optionsDownload full-size imageDownload as PowerPoint slide