| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1332115 | Journal of Solid State Chemistry | 2006 | 5 Pages |
Ferromagnetic-phase transition in spinel-type CuCr2Te4 has been clearly observed. CuCr2Te4 is a telluride–spinel with the lattice constant a=11.134Å, which has been synthesized successfully. The heat capacity exhibits a sharp peak due to the ferromagnetic-phase transition with the Curie temperature TC=326K. This value of TC corresponds exactly to that of the negative peak of dM/dT in low field of 1.0 Oe. The magnetic susceptibility shows the Curie–Weiss behavior between 380 and 650 K with the effective magnetic moment μeff=4.14μB/Cr-ion and the Weiss constant θ=+357K. The low temperature magnetization indicates the spin-wave excitations, where the existence of first term of Bloch T3/2 law and the next T5/2 term are verified experimentally. This spin-wave excitation is detected up to approximately 250 K which is a fairly high temperature.
Graphical abstractMolar heat capacity of CuCr2Te4 over a wide temperature range of 2.17–373 K.Figure optionsDownload full-size imageDownload as PowerPoint slide
