Fabrication and luminescent properties of the core–shell structured YNbO4:Eu3+/Tb3+@SiO2 spherical particles

The core–shell structured YNbO4:Eu3+/Tb3+@SiO2 particles were realized by coating the YNbO4:Eu3+/Tb3+ phosphors onto the surface of spherical silica via a sol–gel process. The obtained materials were characterized by means of X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier transform IR spectroscopy (FT-IR), photoluminescence (PL) spectra, and cathodoluminescence (CL) spectra. The results indicate that 600 °C annealed samples consist of amorphous silica core and crystalline YNbO4:Re shell, having perfect spherical morphology with uniform size distribution. Upon excitation by UV or electron beam, these phosphors show the characteristic 5D0–7F1–4 emission lines of Eu3+ and the characteristic 5D4–7F3–6 emission lines of Tb3+. The PL intensities of Eu3+ can be tuned by altering the annealing temperature and the coating number of YNbO4:Eu3+ layers.

Graphical abstractYNbO4:Eu3+/Tb3+ layers were deposited on spherical SiO2 particles via a sol–gel process, resulting in the formation of core–shell structured YNbO4:Eu3+/Tb3+@SiO2 phosphors. The luminescence properties of phosphors in the core–shell particles can be tuned by altering the annealing temperature and the coating layers of the phosphors.Figure optionsDownload full-size imageDownload as PowerPoint slide