Alpha-particle-induced luminescence of rare-earth-doped Y2O3 nanophosphors

The feasibility of utilizing Y2O3:Tb3+ and Y2O3:Eu3+ as radioluminescent nanophosphors under alpha-particle excitation is investigated. Materials synthesized by the urea homogeneous precipitation method were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The XRD analysis of as-produced precipitates and nanophosphors fired at temperatures ranging from 950 to 1100 °C indicated the presence of highly crystalline cubic Y2O3 with crystallite sizes of ∼40 nm. SEM and TEM analysis revealed that particles with average diameters of ∼200 nm and comprised of ∼40 nm grains were obtained. High-resolution radioluminescence and photoluminescence spectra were used to investigate the unwanted radioluminescence saturation effects associated with the high ionization rate of alpha-particles. Additionally, the radioluminescence intensity as a function of rare-earth ion dopant concentration is investigated for these materials under alpha-particle excitation. The prospect for utilizing these materials as intermediate absorbers in indirect-conversion radioisotope batteries is discussed.

Graphical abstractThe photoluminescence and radioluminesce emission from rare-earth doped Y2O3 nanophosphors are being investigated. Below is a representative image of the photoluminescence from Y2O3:Eu3+ (left) and Y2O3:Tb3+ (right) under UV-light excitation.Figure optionsDownload full-size imageDownload as PowerPoint slide