Fully reversible hydrogen absorption and desorption reactions with Sc(Al1−xMgx), x=0.0, 0.15, 0.20

The hydrogen storage properties of Sc(Al1−xMgx), x=0.0, 0.15, 0.20, have been studied by X-ray powder diffraction, thermal desorption spectroscopy, pressure-composition-isotherms and scanning electron microscopy techniques. Hydrogen is absorbed from the gas phase at 70 kPa and 400 °C under the formation of ScH2 and aluminium with magnesium in solid solution. The reaction is fully reversible in vacuum at 500 °C and shows the hydrogenation–disproportionation–desorption-recombination (HDDR) behaviour. The activation energy of desorption was determined by the Kissinger method to 185 kJ/mol. The material is stable up to at least six absorption–desorption cycles and there is no change in particle size during cycling.

Graphical abstractXRD pattern of Sc(Al1−xMgx). From the top: x=0, 0.15, 0.20. The hydrogen absorption properties were studied by thermal desorption spectroscopy, pressure-composition-isotherms and scanning electron microscopy techniques.Figure optionsDownload full-size imageDownload as PowerPoint slide