Diffusion and phase transformations in spark plasma synthesized and sintered Cu–V2O5 couples

Fast diffusion of Cu into V2O5 at 520 °C is studied in Cu–V2O5 diffusion couples sintered by spark plasma sintering. The impact, on the diffusion profiles, of phase transformations and of variations of the diffusion coefficient with Cu concentration is discussed. From the pure Cu source, two phases are observed to spread, leading to a “two-step-like” shape of the diffusion profiles. In the more concentrated phase (phase ε), the diffusion coefficient D of Cu is ≈3×10−8 m2/s. This is a remarkably high value, of the same order of magnitude as self-diffusion in liquid metals. In the less concentrated phase (phase β′), D is lower than in ε. This is due to the differences in the diffusion mechanisms of Cu in these two phases: two dimensional in ε and one dimensional in β′. In β′, D strongly depends on Cu concentration. This is in good agreement with computer simulations reported in the literature.

Graphical abstractFast diffusion of Cu into V2O5 is studied on Cu–V2O5 diffusion couples sintered by spark plasma sintering. The shape of the diffusion profiles is explained by the influence of phase transitions and by the concentration dependence of the diffusion coefficient. High value of diffusion coefficient is measured (D≈3×10−8 m2/s).Figure optionsDownload full-size imageDownload as PowerPoint slide