Article ID Journal Published Year Pages File Type
1332425 Journal of Solid State Chemistry 2010 10 Pages PDF
Abstract
Antimony silicate glasses have been shown to contain Sb3+ in [:SbO3] trigonal pyramid units using 121Sb Mössbauer spectroscopy and Raman spectroscopy. 29Si magic-angle-spinning NMR has shown silicon Qn speciation which can be interpreted as formation of rings of 4 [:SbO3] units such as are found in valentinite.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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