Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1332443 | Journal of Solid State Chemistry | 2010 | 8 Pages |
The aim of our study was to modify the basis compound ß-TaON, which crystallizes in the monoclinic baddeleyite-type, by incorporation of appropriate dopant ions, in order to obtain anion-deficient cubic fluorite-type phases, which are of interest as solids with mobile nitrogen ions. For this purpose, scandium-doped tantalum oxide nitrides were prepared by ammonolysis of amorphous oxide precursors. An unexpected variety of phases with different structural features was observed: bixbyite-type phases of general composition ScxTa1−x(O,N)y with 0.33≤x≤1 and 1.7≤y≤1.9, yellow colored metastable anatase-type phases such as Sc0.1Ta0.9O1.2N0.8 or Sc0.15Ta0.85O1.3N0.7 and, additionally, anosovite-type phases ScxTa3−xO2xN5−2x with 0≤x≤1.05. Selected phases were investigated by UV/vis spectroscopy. Anatase- and anosovite-type compounds show brilliant colors. In the anatase-type phase, a possible anion ordering was examined by theoretical methods. Additionally, energy calculations on phase stability were performed for ScxTa1−xO1+2xN1−2x in the baddeleyite, rutile, and anatase structure types with varying amounts of dopants.
Graphical abstractNew anatase- and bixbyite-type phases obtained as single-phase samples in the system Sc–Ta–O–N.Figure optionsDownload full-size imageDownload as PowerPoint slide