Second order incommensurate phase transition in 25L-Ta2O5

A new structural state 25L-Ta2O5, obtained from sintering and annealing treatments of a Ta2O5 powder, is identified both by electron diffraction and high resolution imaging on a transmission electron microscope (TEM). According to general rules for the different L-Ta2O5 structures proposed by Grey et al. (J. Solid State Chem. 178 (2005) 3308), a structural model is derived from their crystallographic data on 19L-Ta2O5. This model yields simulated images in agreement with high resolution TEM observations of the structure oriented along its [001] zone axis, but only for a very thin crystal thickness of less than 1.2 nm. Such a limitation is shown to be due to a modulation of the structure along its [001] axis. Actually, from an analysis of a diffuse scattering and of its evolution into satellites reflections as a function of the cooling rate, a second order incommensurate phase transition can be assumed to occur in this compound. The property of single phase samples observed by TEM is also verified by X-ray powder diffraction. In a discussion about studies performed by different authors on incommensurate structures in the system Ta2O5–WO3, it is noticed that TEM results, similar to ours, indicate that phase transitions could be expected in these structures.

Graphical AbstractElectron diffraction patterns of [100] zone axis, showing a structural change of the 25L-Ta2O5 phase through a variation of the cooling rate from 1000 °C.Figure optionsDownload full-size imageDownload as PowerPoint slide