| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1332482 | Journal of Solid State Chemistry | 2008 | 5 Pages |
The new compound Bi2/3Ce1/3Rh2O5 has been discovered. It is currently the only known compound in the Bi–Ce–Rh–O system, and it crystallizes in a previously unknown structure type. The structure was established from single crystal X-ray diffraction data. Interatomic distances indicate the oxidation states as Bi2/33+Ce1/34+Rh23.33+O5. The structure indicates no ordering between Rh3+ and Rh4+. The lack of charge ordering is consistent with the metallic properties determined from electrical conductivity, Seebeck coefficient, and magnetic susceptibility measurements.
Graphical abstractThe new compound Bi2/3Ce1/3Rh2O5 has been discovered. The structure indicates no ordering between Rh3+ and Rh4+. The lack of charge ordering is consistent with the metallic properties determined from electrical conductivity, Seebeck coefficient, and magnetic susceptibility measurements.Figure optionsDownload full-size imageDownload as PowerPoint slide
