| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1332633 | Journal of Solid State Chemistry | 2007 | 5 Pages |
Abstract
The metal-rich part of the LiBaN system was investigated using powder and single-crystal X-ray diffraction analysis. The crystal structures of two new ternary subnitrides, LiBa2N and of LiBa3N, were determined from single-crystal and powder X-ray diffraction data, respectively. LiBa2N has a tetragonal structure (space group, P42/nmc, Z=8, a=7.980(1), c=14.263(2) Å). The structure contains infinite mutually perpendicular rows of edge-sharing LiBa5N octahedra. LiBa3N is isostructural with NaBa3N (P63/mmc, Z=2, a=8.182(1), c=6.922(4) Å).
Graphical abstractTetragonal unit cell of LiBa2N.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Volodymyr Smetana, Volodymyr Babizhetskyy, Grigori V. Vajenine, Arndt Simon,