Structural and magnetic characterisation of CoSb2O4, and the substitution of Pb2+ for Sb3+

The nuclear and magnetic structures of the synthetic schafarzikite related material CoSb2O4 have been determined from neutron powder diffraction data. The compound is tetragonal (P42/mbc) with refined lattice constants at 300 K of, a=8.49340(9) Å, c=5.92387(8) Å. The magnetic ordering is shown to be consistent with a C mode with moments aligned along [0 0 1]. Magnetic susceptibility measurements indicate a canted antiferromagnetic ground state, for which the ferromagnetic component shows unusually high coercivity. The thermal stability of CoSb2O4 in air is reported. The substitution of Pb2+ for Sb3+ has been investigated and found to cause oxidation of both Co2+ to Co3+ and Sb3+ to Sb5+.

Graphical AbstractStructural changes on substitution of Pb2+ ions for Sb3+ ions in CoSb2O4.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The structural details of CoSb2O4 are reported for the first time. ► The magnetic structure of CoSb2O4 are reported for the first time. ► The ordered magnetic structure has a canted antiferromagnetic arrangement. ► The ferromagnetic component of the ordered arrangement has high coercivity. ► Pb2+ can substitute for Sb3+ and oxidation of both Co2+ and Sb3+ occurs.