| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1332693 | Journal of Solid State Chemistry | 2012 | 7 Pages |
In this study, Zn-substituted polycrystalline skutterudites CeFe4−xZnxSb12 (x=0, 0.05, 0.1, 0.2, 0.3) were successfully prepared by a traditional melting–annealing method. The solubility of Zn in Fe site is ∼1.2%, exceeding which trace amount of ZnSb phase can be detected in the XRD. This ZnSb impurity phase, with size of several hundred nanometers for the sample with x=0.2 but showing surprisingly small size of ∼10 nm for the sample with x=0.3, selectively distributes on the grain boundaries. In particular, the introduction of Zn in Fe site effectively improves the Seebeck coefficient in a manner of enhancement in hole effective mass, but it has negligible influence on both electrical and thermal conductivities though the hole concentration is increased. Consequently the corresponding improvement in power factor leads to an improved thermoelectric figure of merit (ZT) of 0.9 at 800 K for the sample with x=0.1, which is ∼15% higher than that of Zn-free sample. This study demonstrates a favorable effect of Zn iso-substitution and opens a new strategy to improve the thermoelectric properties of p-type Fe-based skutterudites beyond the sole phonon engineering.
Graphical abstract(a)–(c) ZnSb nanoinclusions emerge when Zn exceeds its solubility limit. (d), (e) The introduction of Zn boosts the Seebeck coefficient and thus enhances the ZT value.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Zn is successfully employed to substitute Fe atom for the first time. ► ZnSb nanoinclusions emerge when Zn exceeds its solubility limit ∼0.12. ► The introduction of Zn boosts the Seebeck coefficient and enhances the ZT value.
