Visible and infrared luminescence properties of Er3+-doped Y2Ti2O7 nanocrystals

Er3+-doped Y2Ti2O7 nanocrystals were fabricated by the sol–gel method. While the annealing temperature exceeds 757 °C, amorphous pyrochlore phase ErxY2−xTi2O7 transfers to well-crystallized nanocrystals, and the average crystal size increases from ∼70 to ∼180 nm under 800–1000 °C/1 h annealing. ErxY2−xTi2O7 nanocrystals absorbing 980 nm photons can produce the upconversion (526, 547, and 660 nm; 2H11/2→4I15/2, 4S3/2→4I15/2, and 4F9/2→4I15/2, respectively) and Stokes (1528 nm; 4I13/2→4I15/2) photoluminescence (PL). The infrared PL decay curve is single-exponential for Er3+ (5 mol%)-doped Y2Ti2O7 nanocrystals but slightly nonexponential for Er3+ (10 mol%)-doped Y2Ti2O7 nanocrystals. For 5 and 10 mol% doping concentrations, the mechanism of up-converted green light is the two-photon excited-state absorption. Much stronger intensity of red light relative to green light was observed for the sample with 10 mol% dopant. This phenomenon can be attributed to the reduced distance between Er3+–Er3+ ions, resulting in the enhancement of the energy-transfer upconversion and cross-relaxation mechanisms.

Graphical AbstractEmission fluorescence spectra of the Er3+ (3, 5, 7, or 10 mol%)-doped Y2Ti2O7 nanocrystals annealed at 800 °C for 1 h under 980 nm pumping. The Er3+-doped Y2Ti2O7 nanocrystals absorbing 980 nm photons can produce the upconversion (526, 547, and 660 nm; 2H11/2→4I15/2, 4S3/2→4I15/2, and 4F9/2→4I15/2, respectively) and Stokes (1528 nm; 4I13/2→4I15/2) photoluminescence.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Er0.05Y0.95Ti2O7 nanocrystals annealed at 800 °C exhibit the crystalline pyrochlore structure. ► Er0.05Y0.95Ti2O7 nanocrystals possess the maximum upconversion and Stokes PL intensities. ► The upconversion mechanism of Er0.05Y0.95Ti2O7 are the two-photon excited-state absorption.