In situ X-ray absorption spectroscopic investigation of the electrochemical conversion reactions of CuF2–MoO3 nanocomposite

We have used X-ray absorption spectroscopy at the Cu K-edge to investigate the electrochemical conversion reaction of 20 nm size 85 wt% CuF2−15 wt% MoO3 nanocomposite under in situ conditions. The nanocomposite was prepared by high energy milling. Upon discharge, the lithiation reaction with the nanocomposite resulted in the formation of nanophase metallic Cu, which is consistent with the conversion of CuF2 into Cu and LiF. Based on XANES and Fourier transforms of EXAFS spectra, we show that the discharge process proceeded via the formation of highly dispersed Cu particles. Based on the coordination number of the first shell of Cu, the average size of the Cu particles was estimated to be in the 1–3 nm range in the fully discharged state.

Graphical AbstractComparison of Fourier transform of in situ Cu K-edge EXAFS spectra for a fully discharged CuF2•MoO3 nanocomposite in a nonaqueous Li cell with that of a Cu foil. Quantitative analysis of the Fourier transforms confirmed that the discharge mechanism for the nanocomposite proceeds via the reaction CuF2+2Li→Cu+2LiF. The discharge product of Cu is in the form of highly dispersed nanoparticles.Figure optionsDownload full-size imageDownload as PowerPoint slide