Article ID Journal Published Year Pages File Type
1333507 Journal of Solid State Chemistry 2006 5 Pages PDF
Abstract

A novel blue-emitting phosphor, LiSrPO4:Eu2+, was prepared by the solid-state reaction and X-ray powder diffraction (XRD) analysis confirmed the formation of LiSrPO4:Eu2+. Photoluminescence (PL) results showed that the phosphor can be efficiently excited by UV-visible light from 250 to 440 nm, and exhibited bright blue emission. The effects of the doped-Eu2+ concentration in LiSrPO4:Eu2+ on the PL were investigated in detail. The results showed that the relative PL intensity increases with Eu2+-concentration increasing until a maximum intensity is reached, and then it decreases due to concentration quenching and a red-shift appears, which are explained satisfactorily with the luminescent theory. Upon excited with 396 nm light, the present synthesized phosphor has higher emission intensity than that from the commercial blue phosphor, BaMgAl10O17:Eu2+. Bright blue light-emitting diodes were fabricated by the combination of the synthesized LiSrPO4:Eu2+ with ∼397 nm emitting InGaN-based chips.

Graphical abstractThe EL spectrum of the blue LED-based LiSrPO4:Eu2+.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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