Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1333581 | Journal of Solid State Chemistry | 2009 | 7 Pages |
From neutron diffraction data collected at 3 K on a powder of La9.67(SiO4)6O2.5 composition and a careful examination of the average structure, a model was proposed to explain the oxygen over-stoichiometry in the apatite structure. This model leads to realistic distances to neighbouring atoms. Moreover, it accounts perfectly for the maximum oxygen content observed in these materials. Up to 0.5 oxygen atom located at the vicinity of the 2a site (0, 0, 14) would be shifted to a new interstitial position in the channel at (−0.01, 0.04, 0.06), creating a Frenkel defect, with the possibility of a maximum occupancy in this site equal to twice the Frenkel defect numbers. This structural model is in good agreement with the oxygen diffusion pathways recently proposed by Bechade et al. (2009) using computer modeling techniques. It supports preferred oxygen diffusion pathways via interstitial oxygen atoms and vacant sites along [0 0 1], close to the centre of the La(2)-O channels.
Graphical abstract legendStructural defect position and possible conduction mechanism along the c-axis (representation of two adjacent unit-cells)Figure optionsDownload full-size imageDownload as PowerPoint slide