| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1333609 | Journal of Solid State Chemistry | 2006 | 5 Pages |
Abstract
A new 1D complex has been prepared and characterized. X-ray single crystal structure confirms that the Mn(II) ions assemble in alternating chains with Mn–Mn distances of 3.8432(13) and 4.4428(14) Å. A 3D network of hydrogen bonds links the chains together. The temperature dependence of the magnetic susceptibility reveals that this compound undergoes a magnetic transition and exhibits an antiferromagnetic interaction in the low-temperature phase with two alternating exchange interactions of −2.32(1) and −5.55(1) cm−1.
Graphical abstractPortion of the dimeric manganese chain showing the two alternating exchange interactions paths.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Manuela Ramos Silva, Ana Matos Beja, José António Paixão, Jesus Martín-Gil,