Recent developments in synthetic approaches to transition metal phosphide nanoparticles for magnetic and catalytic applications

Recent advances in synthetic methods have led to the preparation of a wide array of transition metal phosphide nanoparticles, and characterization of these materials has provided insight into nanoscale magnetic and catalytic properties. This review highlights advances in the field that have been made since the time of the last review [S.L. Brock, S.C. Perera, K.L. Stamm, Chem. Eur. J. 10(2004)3364–3371]. Synthetic methods include solvothermal, solution-phase arrested precipitation, metal nanoparticle conversion, and phosphate reduction. Magnetic properties of FeP, Fe2P and MnP nanoparticles and nanorods (among others), and recent data on thiophene hydrodesulfurization catalyzed by discrete, unsupported Ni2P particles, is presented. Finally, the future prospects for the field are discussed.

Graphical abstractRecent advances in synthetic methods have led to the preparation of a wide array of transition metal phosphide nanoparticles, and characterization of these materials has provided insight into nanoscale magnetic and catalytic properties. This paper highlights advances in the field that have been made since 2004.Figure optionsDownload full-size imageDownload as PowerPoint slide