Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1333747 | Journal of Solid State Chemistry | 2008 | 4 Pages |
Magnetic properties of Mn2V2O7 single crystals are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. A structural phase transition of the α–β forms is clearly observed at the temperature range of 200–250 K and an antiferromagnetic ordering with magnetic anisotropy is observed below 20 K. A spin-flop transition is observed with magnetic field applied along the [110] axis of β-Mn2V2O7, of which corresponds to the [001] axis of α-Mn2V2O7, suggesting that the spins of Mn2+ ions locate within honeycomb layers which point likely in the [110] direction of β-Mn2V2O7 or the [001] axis of α-Mn2V2O7. However, a rather small jump of magnetization at spin-flop transition suggests a possible partition of crystal to some domains through β-to-α transition on cooling or much complex spin structure in honeycomb lattice with some frustration.
Graphical abstractA structural phase transition of the α–β forms occurs at 200–250 K and an antiferromagnetic ordering occurs at ∼20 K. A field-induced spin-flop transition shows that spins of Mn2+ ions in Mn2V2O7 may locate within honeycomb layers.Figure optionsDownload full-size imageDownload as PowerPoint slide