In situ neutron powder diffraction investigation of the hydration of tricalcium aluminate in the presence of gypsum

The hydration of a 1:3 molar ratio of tricalcium aluminate, Ca3Al2O6, to gypsum, CaSO4·2D2O, was investigated at temperatures of 25, 50, and 80 °C using time-of-flight powder neutron diffraction combined with multiphase Rietveld structural refinement. It was shown that ettringite, Ca6[Al(OD)6]2(SO4)3·∼26D2O, was the first and only hydration product of the system, in contrast to a prior investigation which suggested the occurrence of a precursor phase prior to the formation of ettringite. Kinetics data showed that the hydration reaction is very sensitive to temperature: hydration at 25 °C was characterized by a single kinetic regime while hydration at higher temperatures consisted of two distinct kinetic regimes. The presence of two kinetic regimes was attributed to a change in either the dimensionality of the growth process or a change in the rate controlling mechanism in the hydration reaction.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide