Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1334135 | Journal of Solid State Chemistry | 2005 | 19 Pages |
Abstract
Copper(II) terephthalate is the first transition metal complex found capable of adsorbing gases. This complex has opened the new field of adsorbent complex chemistry. It is recognized as the lead complex in the construction of microporous complexes. This specific system has been expanded to a systematic series of derivatives of other isomorphous transition metals, molybdenum(II), ruthenium(II, III), and rhodium(II). These complexes with open frameworks are widely recognized as very useful materials for applications to catalysis, separation at molecular level, and gas storage.
Graphical abstractNovel microporous intramolecular reaction systems.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Wasuke Mori, Tomohiko Sato, Tesushi Ohmura, Chika Nozaki Kato, Tohru Takei,