| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1342677 | Polyhedron | 2017 | 7 Pages |
Abstract
The reaction between [Y(NCS)3(phen)3] (phen = 1, 1 0-phenanthroline) and K(HBpz3) (pz = pyrazol-1-yl) afforded the binuclear hydroxo-bridged complex [Y(HBpz3)(NCS)(μ-OH)(phen)]2, the crystal structure of which reveals that the eightcoordinate yttrium atoms have a distorted square antiprismatic geometry with a nonlinearly nitrogen-bonded thiocyanate [Y—N—C(S) = 149.0(6)o] ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Heteroleptic trispyrazolylborate complexes of yttrium: The synthesis and x-ray crystal structure of a binuclear o-phenanthroline complex [Y(HBpz3)(NCS)(μ-OH) (phen)]2]](/preview/png/1342677.png "First Page Preview: Heteroleptic trispyrazolylborate complexes of yttrium: The synthesis and x-ray crystal structure of a binuclear o-phenanthroline complex [Y(HBpz3)(NCS)(μ-OH) (phen)]2]")