Article ID Journal Published Year Pages File Type
1343957 Tetrahedron: Asymmetry 2013 6 Pages PDF
Abstract
A perfect temperature-guided diastereoselectivity switch was observed in the desymmetrization of some meso-bridged tricyclic succinic anhydrides with a lithiated chiral 5,5-disubstituted oxazolidin-2-one called SuperQuat. Experimental conditions required for the optimum diastereoselectivity and to obtain the individual diastereoisomers of the SuperQuat linked meso-anhydride opening products with acceptable purity and yield have been established.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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