| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1344266 | Tetrahedron: Asymmetry | 2012 | 6 Pages |
Abstract
The enantioselective carbon–boron bond oxidation of several chiral boron-containing compounds by Baeyer-Villiger monooxygenases was evaluated. PAMO and M446G PAMO conveniently oxidized 1-phenylethyl boronate into the corresponding 1-(phenyl)ethanol (ee = 82–91%). Cyclopropyl boronic esters were also oxidized but with no enantioselectivity. β-Boryl carboxylic esters were not oxidized by any BVMOs.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Patrícia B. Brondani, Hanna Dudek, Joel S. Reis, Marco W. Fraaije, Leandro H. Andrade,