Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1344725 | Tetrahedron: Asymmetry | 2010 | 4 Pages |
Abstract
The enantioselective hydrogenation catalyst [Rh(α-CgPH)2(cod)]BF4, (CgPH = 6-phospha-2,4,8-trioxa-adamantane) exists in solution as a mixture of two slowly interconverting rotamers, one with C2- and the other with C1-symmetry.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Piotr Jankowski, Claire L. McMullin, Ilya D. Gridnev, A. Guy Orpen, Paul G. Pringle,