| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1344729 | Tetrahedron: Asymmetry | 2010 | 6 Pages |
Abstract
The complexes [Rh((S)-BINAP)(COD)]BF41, [Rh((S)-BINAP)(NBD)]BF42, [Rh((R)-BINAP)(COD)]OTf 3, [Rh((R)-BINAP)(NBD)]OTf 4, and [Rh((R)-BINAP)(COD)]BArF 5 were synthesized, and 1–4 were analyzed by single crystal X-ray crystallography. The transformation of these precatalysts into hydrogenation-active species was investigated as well as the hydrogenation of prochiral olefins. In particular, this series of transformations was investigated with regard to solvent and counterions.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Angelika Preetz, Hans-Joachim Drexler, Stefan Schulz, Detlef Heller,