Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1345484 | Tetrahedron: Asymmetry | 2007 | 5 Pages |
Abstract
The catalytic activity of several organometallic derivatives of polyoxometalates, especially those of general formula [M4O16{M′(η6-arene)}4] (M = Mo, W; M′ = Ru, Os), was evaluated in the racemization of secondary alcohols. A link between composition, fluxionality and catalytic activity was established.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Danielle Laurencin, Richard Villanneau, Anna Proust, Anne Brethon, Isabel W.C.E. Arends, Roger A. Sheldon,