| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1346388 | Tetrahedron: Asymmetry | 2011 | 5 Pages |
Abstract
The hydrobromide and nitrate of 4-(tert-butyl)-5-(4-chlorobenzyl)thiazol-2-amine have been synthesized, and their chiral symmetry breaking in the solid-state has been investigated. It is shown that each molecule is connected by continuous N–H···Br/N–H···O hydrogen bonds to afford left- or right-handed helical assemblies in the crystal packing. Mirror-image CD spectra were obtained for the right- and left-handed helical-type chiral crystals.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Aixi Hu, Gao Cao,