| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1346993 | Tetrahedron: Asymmetry | 2010 | 6 Pages |
Abstract
Novel camphor sulfonamide based organocatalysts were evaluated for their catalytic activity in the Michael reaction of ketones with nitroolefins. Reaction of ketones with β-nitrostyrenes in the presence of 20 mol % organocatalyst 1a and benzoic acid under solvent-free conditions at 0 °C provided the desired Michael adducts with high chemical yields (up to 97%) and excellent stereoselectivities (>99:1).
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Rashmi Rani, Rama Krishna Peddinti,