| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1347027 | Tetrahedron: Asymmetry | 2009 | 5 Pages |
The components of the pheromone blend of Mayetioladestructor, Drosophilamulleri, and Contariniapisi were synthesized in high enantiomeric excess (99% ee) from a common enantiopure dianion prepared from an enantiopure hydroxytelluride.
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(S,E)-Tridec-10-en-2-yl acetateC15H28O2Ee = 99%[α]D22=+0.95 (c 1.02, CHCl3)Source of chirality: enantiopure hydroxytellurideAbsolute configuration: (2S)
(S,E)-Tridec-10-en-2-olC13H26OEe = 99%[α]D20=+6.8 (c 1.00, CHCl3)Source of chirality: enantiopure hydroxytellurideAbsolute configuration: (2S)
(2S,12S)-Tridecane-2,12-diyl diacetateC17H32O4Ee = 99%[α]D20=+2.0 (c 1.20, CHCl3)Source of chirality: enantiopure hydroxytellurideAbsolute configuration: (2S,12S)
(S)-Tridecan-2-yl acetateC15H30O2Ee = 99%[α]D20=+4.5 (c 1.00, hexane)Source of chirality: enantiopure hydroxytellurideAbsolute configuration: (2S)
