Article ID Journal Published Year Pages File Type
1347269 Tetrahedron: Asymmetry 2009 6 Pages PDF
Abstract

Polyleucines of various lengths act as enantioselective catalysts in the aldol condensation between cyclohexanone and various aromatic aldehydes. Polyleucine and other polyamino acids behave as synthetic enzymes in the epoxidation of chalcone and other electron-deficient alkenes. Both reactions are of considerable prebiotic significance.

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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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