| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1347360 | Tetrahedron: Asymmetry | 2014 | 7 Pages |
Abstract
A new inherently chiral calix[4]arene ICC 1 has been disclosed. The dissymmetry of 1 is generated from a chirality plane in the quinol moiety of a 1,3-bridged bicyclic calix[4]arene. ICC 1 has been resolved by enantioselective HPLC, and the chiroptical properties of both isolated antipodes (pS)-1 and (pR)-1 confirm their enantiomeric nature. The absolute configuration of the (pS)-1/(pR)-1 enantiomeric pair was established through time-dependent density functional theory (TDDFT) calculations of electronic circular dichroism (CD) spectra.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
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Authors
José V. Prata, Alexandra I. Costa, Gennaro Pescitelli, Carlos M. Teixeira,