Article ID Journal Published Year Pages File Type
1348156 Tetrahedron: Asymmetry 2006 4 Pages PDF
Abstract

Chiral enantiopure secondary phospholane 1-r-H-2-c,5-t-diphenylphospholane and the corresponding oxide are unusual and efficient ligands in the rhodium catalyzed hydrogenation of olefins.

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(2S,5S)-(+)-2,5-DiphenylphospholaneC16H17P[α]D20=+104 (c 0.95, CHCl3)Absolute configuration: (2S,5S)

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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