Article ID Journal Published Year Pages File Type
1348270 Tetrahedron: Asymmetry 2007 4 Pages PDF
Abstract
The diastereoselective reactions of palladium acetate with (η5-(S)-2-(4-methylethyl)oxzazolinylcyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt, which gives a planar chiral palladacycle with (pR) configuration, and (η5-(S)-2-(4-dimethylethyl)oxzazolinylcyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt, which results in the opposite (pS) configuration, are shown to be a consequence of these reactions displaying thermodynamic and kinetic control, respectively.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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