Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1348409 | Tetrahedron: Asymmetry | 2007 | 4 Pages |
Abstract
The enantioselective kinetic resolution of two 3-phenyl-2-ketones using four different Baeyer–Villiger monooxygenases (BVMO) expressed recombinantly in Escherichia coli was studied. The highest enantioselectivity (E = 82) was achieved for 3-phenyl-2-butanone using a BVMO originating from Pseudomonas fluorescens. A BVMO from Pseudomonas putida showed an opposite (R)-enantiopreference and E = 12.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kristian Geitner, Anett Kirschner, Jessica Rehdorf, Marlen Schmidt, Marko D. Mihovilovic, Uwe T. Bornscheuer,