Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1348420 | Tetrahedron: Asymmetry | 2007 | 7 Pages |
Abstract
The ability of commercially available amino acid derivatives, especially Fmoc-Trp(Boc)-OH, to differentiate enantiomers of chiral phosphonates, phosphinates, phosphates, phosphine oxides, and phosphonamidates is demonstrated with 31P, 13C, and 1H NMR spectroscopy. The chiral differentiation provided a rapid and convenient method for measuring the enantiomeric purity of these phosphorus compounds.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yingchun Li, Frank M. Raushel,