Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1348927 | Tetrahedron: Asymmetry | 2005 | 5 Pages |
Abstract
The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Carla Estivill, Marta Pomares, Martin Kotev, Petko Ivanov, Albert Virgili,