Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1348995 | Tetrahedron: Asymmetry | 2010 | 5 Pages |
Abstract
Monodentate binaphthophosphepines (BINEPINES) have been tested in the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenylallyl esters. Stereoselectivities of up to 92% ee have been achieved in the alkylation of the acetate ester with the C-nucleophile, generated in situ by the action of BSA (N,O-bis(trimethylsilyl)acetamide) on dimethylmalonate in the presence of a catalytic amount of sodium acetate.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Elisabetta Alberico, Serafino Gladiali, Rossana Taras, Kathrin Junge, Matthias Beller,