| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1349052 | Tetrahedron: Asymmetry | 2010 | 14 Pages |
Abstract
Diastereoselective sulfur oxidation in 2-thio-3-chloroacrylamides is described. A range of chiral amine auxiliaries was incorporated in the β-chloroacrylamide, and the efficiency with which the stereochemistry was relayed to the sulfur centre during sulfoxidation was investigated. Diastereomeric ratios of up to 3.3:1 were achieved.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Marie Kissane, Simon E. Lawrence, Anita R. Maguire,