| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1349301 | Tetrahedron: Asymmetry | 2005 | 6 Pages |
Abstract
Racemic 1,2-epoxy-3-(2-methoxyphenyloxy)-propane 1 undergoes spontaneous resolution upon crystallization. This fact is confirmed by coincidence of the IR spectra of racemic and scalemic crystalline samples of 1, by thermal analysis (single eutectic V-shape binary melting phase diagram), and X-ray analysis (space group P212121, ZÂ =Â 4). Racemic 1 could be resolved into (S)-(+)- and (R)-(â)-1 by a preferential crystallization procedure.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Alexander A. Bredikhin, Elena I. Strunskaya, Dmitry V. Zakharychev, Dmitry B. Krivolapov, Igor A. Litvinov, Zemfira A. Bredikhina,