Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1350692 | Tetrahedron: Asymmetry | 2006 | 7 Pages |
Abstract
The absolute configuration and enantiomeric excess of chiral cyclic alcohols can be predicted from the 31P NMR spectra of the two diastereoisomers obtained with organophosphorus diamino-derivatizing agents (CDAs) and the chiral secondary alcohol, according to a simplified model taking into account the spatial location of the substituents of the chiral alcohol center and the 31P NMR signals of the two diastereoisomers.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Anne-Sophie Chauvin, Gérald Bernardinelli, Alexandre Alexakis,