| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1350873 | Tetrahedron: Asymmetry | 2005 | 5 Pages |
Abstract
The synthesis of a new generation of chiral phosphine-amides derived from d-glucosamine is described. The palladium-catalyzed asymmetric allylic alkylation of racemic 1,3-diphenyl-2-propenyl acetate with dimethyl malonate has been investigated. The results obtained from these new ligands showed the importance of the rigidity of the complex and of the d-glucosamine skeleton on the enantioselectivity of the reaction.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Anzhelika Konovets, Katarzyna GlegoÅa, Alexandra Penciu, Eric Framery, Philippe Jubault, Catherine Goux-Henry, K. MichaÅ Pietrusiewicz, Jean-Charles Quirion, Denis Sinou,