| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1350878 | Tetrahedron: Asymmetry | 2005 | 8 Pages |
Abstract
Optically active phosphite-type ligands with planar chirality have been synthesized for the first time. The new cymantrene-based P,N-iminodiamidophosphites demonstrated high enantioselectivity in the Pd-catalyzed allylic substitution of 1,3-diphenylallyl acetate with dimethyl malonate (up to 94% ee), pyrrolidine (up to 78% ee) and sodium para-toluene sulfinate (up to 84% ee).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Konstantin N. Gavrilov, Vasily N. Tsarev, Stanislav I. Konkin, Nikolay M. Loim, Pavel V. Petrovskii, Elena S. Kelbyscheva, Alexander A. Korlyukov, Mikhail Yu. Antipin, Vadim A. Davankov,