Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1351024 | Tetrahedron: Asymmetry | 2005 | 7 Pages |
Abstract
Chiral Mn(salen) complexes axially immobilized onto insoluble polymers by phenoxy group or phenyl sulfonic group afford comparable or even higher enantioselectivities than homogeneous Mn(salen) catalysts for the asymmetric epoxidation of various unfunctionalized olefins. These heterogeneous Mn(salen) catalysts are relatively stable and can be recycled in the asymmetric epoxidation.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Huidong Zhang, Yanmei Zhang, Can Li,