| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1384632 | Carbohydrate Research | 2010 | 6 Pages |
Abstract
The aldol reaction between cis-3-((tert-butyldiphenylsilyloxy)methyl)oxirane-2-carbaldehyde and ethyl-2-(trimethylsilyloxy)-2-propenoate promoted by boron trifluoride diethyl etherate was reinvestigated. By varying the work-up conditions, a new 2-deoxy-2-fluoro heptulosonic ester analogue was synthesized. Derivatizations and detailed NMR analysis allowed the complete characterization of this fluoro analogue and its derivatives.
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Authors
Hatim Filali, Mathieu Danel, Stéphanie Ballereau, Michel Baltas,