Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1384813 | Carbohydrate Polymers | 2016 | 8 Pages |
•NMR measurements clarify the process of network formation in mixed CR gel.•Longer chains preferentially form aggregates, reducing average Mw of solute CRs.•Diffusion of a probe indicates IPN or phase separation in mixed CR gels.
The temperature dependencies of the 1H T2 and diffusion coefficient (D) of a mixed solution of kappa-carrageenan and iota-carrageenan were measured by NMR. Rheological and NMR measurements suggested an exponential formation of rigid aggregates of kappa-carrageenan and a gradual formation of fine aggregates of iota-carrageenan during two step increases of G′. The results also suggested that longer carrageenan chains are preferentially involved in aggregation, thus resulting in a decrease in the average Mw of solute carrageenans. The results of diffusion measurements for poly(ethylene oxide) (PEO) suggested that kappa-carrageenan formed thick aggregates that decreased hindrance to PEO diffusion by decreasing the solute kappa-carrageenan concentration in the voids of the aggregated chains, and that iota-carrageenan formed fine aggregates that decreased the solute iota-carrageenan concentration less. DPEO in a mixed solution of kappa-carrageenan and iota-carrageenan suggested two possibilities for the microscopic network structure: an interpenetrating network structure, or micro-phase separation.