Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1385218 | Carbohydrate Research | 2008 | 6 Pages |
Abstract
The 1,3-dipolar cycloaddition of cyclic nitrone derived from tartaric acid and (S)-5-hydroxymethyl-2(5H)-furanone leads to a single adduct which was transformed into 2,6-dihydroxyhastanecine via reaction sequence involving reduction of the lactone moiety, glycolic cleavage of the terminal diol, and the N–O hydrogenolysis followed by the intramolecular alkylation of the nitrogen atom.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sebastian Stecko, Margarita Jurczak, Zofia Urbańczyk-Lipkowska, Jolanta Solecka, Marek Chmielewski,