Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1385484 | Carbohydrate Research | 2007 | 12 Pages |
Abstract
Rapid assembly of starch fragment analogues was achieved using ‘click chemistry’. Specifically, a pentadecasaccharide and two hexadecasaccharide mimics containing two parallel maltoheptaosyl chains linked via [1,2,3]-triazoles to glucose or maltose core were synthesised using Cu(I)-catalyzed [3+2] dipolar cycloaddition of azidosaccharides and 4,6-di-O-propargylated methyl α-d-glucopyranoside and 6,6′- and 4′,6′-di-O-propargylated p-methoxyphenyl β-maltoside.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sergey A. Nepogodiev, Simone Dedola, Laurence Marmuse, Marcelo T. de Oliveira, Robert A. Field,