Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1385494 | Carbohydrate Research | 2007 | 4 Pages |
Abstract
Methanesulfonic acid was shown to be an efficient and convenient substitute for ethereal HCl in reductive 4,6-O-benzylidene acetal ring-opening reaction with sodium cyanoborohydride in THF. Normal regioselectivity was observed, the 6-O-benzyl ethers with free 4-OH group being the major products of the reaction.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Alexander I. Zinin, Nelly N. Malysheva, Anna M. Shpirt, Vladimir I. Torgov, Leonid O. Kononov,